From left to right, light reflecting off surfaces made from aluminum, silicon, and aluminum nitride. At right is a piece of aluminum nitride coated with the new anti-reflection material. Credit: Rensselaer/Fred Schubert

A team of Rensselaer researchers has created the world’s first material that reflects virtually no light. Reporting in the March issue of Nature Photonics, they describe an optical coating made from the material that enables vastly improved control over the basic properties of light. The research could open the door to much brighter LEDs, more efficient solar cells, and a new class of “smart” light sources that adjust to specific environments, among many other potential applications.

Most surfaces reflect some light — from a puddle of water all the way to a mirror. The new material has almost the same refractive index as air, making it an ideal building block for anti-reflection coatings. It sets a world record by decreasing the reflectivity compared to conventional anti-reflection coatings by an order of magnitude. 

A fundamental property called the refractive index governs the amount of light a material reflects, as well as other optical properties such as diffraction, refraction, and the speed of light inside the material. “The refractive index is the most fundamental quantity in optics and photonics. It goes all the way back to Isaac Newton, who called it the ‘optical density,’” said E. Fred Schubert, the Wellfleet Senior Constellation Professor of the Future Chips Constellation at Rensselaer and senior author of the paper.

Schubert and his coworkers have created a material with a refractive index of 1.05, which is extremely close to the refractive index of air and the lowest ever reported. Window glass, for comparison, has a refractive index of about 1.45.

Scientists have attempted for years to create materials that can eliminate unwanted reflections, which can degrade the performance of various optical components and devices. “We started thinking, there is no viable material available in the refractive index range 1.0-1.4,” Schubert said. “If we had such a material, we could do incredible new things in optics and photonics.”

To achieve a very low refractive index, silica nanorods are deposited at an angle of precisely 45 degrees on top of a thin film of aluminum nitride. Credit: Rensselaer/Fred Schubert

So the team created one. Using a technique called oblique angle deposition, the researchers deposited silica nanorods at an angle of precisely 45 degrees on top of a thin film of aluminum nitride, which is a semiconducting material used in advanced light-emitting diodes (LEDs). From the side, the films look much like the cross section of a piece of lawn turf with the blades slightly flattened. 

The technique allows the researchers to strongly reduce or even eliminate reflection at all wavelengths and incoming angles of light, Schubert said. Conventional anti-reflection coatings, although widely used, work only at a single wavelength and when the light source is positioned directly perpendicular to the material.

The new optical coating could find use in just about any application where light travels into or out of a material, including more efficient solar cells, brighter LEDs, optical interconnects, high-reflectance mirrors, and “smart” light sources that offer the potential for totally new functionalities.

The development could also advance fundamental science. A material that reflects no light is known as an ideal “black body.” No such material has been available to scientists, until now. Researchers could use an ideal black body to shed light on quantum mechanics, the much-touted theory from physics that explains the inherent “weirdness” of the atomic realm.

Schubert and his coworkers have only made several samples of the new material to prove it can be done, but the oblique angle evaporation technique is already widely used in industry, and the design can be applied to any type of substrate — not just an expensive semiconductor such as aluminum nitride.

Several other Rensselaer researchers also were involved with the project: Professors Shawn-Yu Lin and Jong Kyu Kim; and graduate students J.-Q. Xi, Martin F. Schubert, and Minfeng Chen.

See campus interview with Fred Schubert.

Listen to Schubert interview on NPR Morning Edition.

Read the press release.

Published March 5, 2007